Eventually, policies like these lead to “don’t hire employees in France”. At which point, no French employees are even bothered by employers on their free time again...
Ah, you say "don't hire employees in France" but it reads "don't grab slaves in France". If worker's rights are an issue for you, those people in France are better without your "job", thank you very much. There are many many other jobs without near-slavery conditions, luckily.
Yes, it exists. Yes, no-one can notify the guy on duty because no-one can send him emails.