I think there's actually some potential here, considering LLMs are already very good at translating text between human languages. I don't think LLMs on their own would be very good, but a specially trained AI model perhaps, such as those trained for protein folding. I think what an LLM could do best is generate better decompiled code, giving better names to symbols, and generating code in a style a human is more likely to write.

I usually crap on things like chatgpt for being unreliable and hallucinating a lot. But in this particular case, decompilers already usually generate inaccurate code, and it takes a lot of work to fix the decompiled code to make it correct (I speak from experience). So introducing AI here may not be such a huge stretch. Just don't expect an AI/LLM to generate perfectly correct decompiled code and we're good (wishful thinking).